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White vinegar is an effective natural cleaner for refrigerators, helping to remove dirt and odors. However, caution is needed to avoid damaging shelves. A mixture of equal parts vinegar and water can clean glass surfaces and sticky residues, but it is not a disinfectant. Special care is required for aluminum edges and rubber seals to prevent damage from acidity. Sudden temperature changes can crack glass shelves, so they should be warmed to room temperature before cleaning. For persistent stains, a warm damp cloth can help, and baking soda paste can be used for tough residues. Vinegar should never be mixed with bleach or hydrogen peroxide due to toxic reactions. Proper cleaning techniques and product instructions should always be followed.